Kinetics and Mechanism of Birnessite Reduction by Catechol
نویسندگان
چکیده
منابع مشابه
Kinetics and Mechanism of Birnessite Reduction by Catechol
and hydroxides containing Mn(III) and Mn(IV) can oxidize organic ligands more rapidly than O2. Aromatic The complex interactions of oxidizable organic ligands with soil and nonaromatic ligands have been reported to dissolve Mn(III,IV) (hydr)oxide minerals have received little study by in situ spectroscopic techniques. We used a combination of an in situ electron reductively Mn(III,IV) (hydr)oxi...
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چکیده هدف از این کار بررسی الکترواکسیداسیون کتکول و مشتقات آن در حضور 4-فنیل سمی کاربامازید بوده است اکسیداسیون کتکولها ترکیبات نا پایدار کینونها را تولید می کنند که این ترکیبات می تواند در واکنش مایکل بعنوان پذیرنده نوکلئوفیل عمل نمایند. در ادامه اکسایش کتکولهای (a-c1) را درحضور 4-فنیل سمی کاربامازید در محلول آب/استونیتریل (90/10)بوسیله ولتامتری چرخه ای و کولن متری در پتانسیل ثابت مورد بررسی ...
15 صفحه اولKinetics and Mechanism of Oxidation of n-Pentanol by Tetramethylammonium Fluorochromate
The oxidation of n-pentanol by tetramethylammonium fluorochromate in acidic solution wasstudied using spectrophotometric technique. The reaction was arranged to be under pseudo firstorderconditions respect to the oxidant. A Michaelis-Menten type kinetic was observed respect tothe substrate. The reaction is catalyzed by hydrogen ions. Dependences of the reaction rates ontemperature and different...
متن کاملAcid Catalysed Condesation of Phloroglucinol and Acetone-Kinetics and Mechanism
The kinetic study of the condensation reaction between phloroglucinol and acetone was investigated at 30, 35, 40 and 45±0.05 °C in 100% methanol. The hydrochloric acid concentrations used were 0.0261, 0.0364, 0.0577 and 0.0728 M. The reaction was investigated with and without a promoter, thioglycollic acid (TGA), and taking into account the functionality (h<e...
متن کاملStudies on the Kinetics and Mechanism of Reduction of Flavodoxin
1 The reactions of the oxidised and semiquinone forms of Peptostreptococcus elsdenii flavodoxin with sodium dithionite have been studied by stopped flow spectrophotometry. At low ionic strength where comproportionation of flavodoxin is slow compared with the overall rate of reduction, the reactions with an excess of dithionite follow first-order kinetics. Semiquinone is not detected during the ...
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ژورنال
عنوان ژورنال: Soil Science Society of America Journal
سال: 2001
ISSN: 0361-5995,1435-0661
DOI: 10.2136/sssaj2001.65158x